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Toothache tends to be worse at night because the brain has fewer activities bothering it at night. When our mind is not very active, the senses are very sensitive, and normal pain during the days turns to be very painful at night.
Garlic contains a compound known as Allicin, which fights bacteria and can relieve toothache at night.
Note that these remedies are not long-term solutions to your toothache; they only provide relief as you wait to see a dentist.